Contributors: Lund University, Faculty of Engineering, LTH, Departments at LTH, Department of Process and Life Science Engineering, Division of Chemical Engineering, Lunds universitet, Lunds Tekniska Högskola, Institutioner vid LTH, Institutionen för processteknik och tillämpad biovetenskap, Avdelningen för kemiteknik, Originator; Lund University, Faculty of Engineering, LTH, LTH Profile areas, LTH Profile Area: Water, Lunds universitet, Lunds Tekniska Högskola, LTH profilområden, LTH profilområde: Vatten, Originator; Lund University, Faculty of Engineering, LTH, LTH Profile areas, LTH Profile Area: The Energy Transition, Lunds universitet, Lunds Tekniska Högskola, LTH profilområden, LTH profilområde: Energiomställningen, Originator
نبذة مختصرة : Zirconia-supported vanadium–copper catalysts (VCux:yZr) were used for the oxidative depolymerization of softwood LignoBoost Kraft lignin (LB). Various VCux:yZr catalysts were prepared (x:y = 0:1, 1:4, 1:2, 3:4, 1:1, and 1:0) by incipient wetness impregnation, and reactions were performed in alkaline water at 150 °C under an O2 pressure of 5 bar for 10 min. 1H–13C HSQC NMR spectroscopy was used for product identification and quantification. The most promising catalyst was VCu1:2Zr, giving a total monomer yield of 9 wt% and the highest selectivity for vanillin (59%). This catalyst was characterized before and after use by N2 physisorption, XRD, TGA, SEM-EDS, and XPS. Cleavage of the main interunit linkages in LB, including the β-O-4 bonds and recalcitrant C–C bonds, was also observed. The findings of this study demonstrate the potential of the V–Cu/ZrO2 catalyst system in the production of value-added aromatics from technical lignin under relatively mild conditions. This would contribute to the more sustainableuse of an underutilized side-stream in forest-based industries, provided catalyst reuse can be successfully demonstrated.
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