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Fluctuations of intensive quantities in statistical thermodynamics

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  • المؤلفون: Ruuge, Artur
  • المصدر:
    1099-4300 ; Entropy: an international and interdisciplinary journal of entropy and information studies
  • الموضوع:
  • نوع التسجيلة:
    article in journal/newspaper
  • اللغة:
    English
  • معلومة اضافية
    • الموضوع:
      2013
    • Collection:
      IRUA - Institutional Repository van de Universiteit Antwerpen
    • نبذة مختصرة :
      In phenomenological thermodynamics, the canonical coordinates of a physical system split in pairs, with each pair consisting of an extensive quantity and an intensive one. In the present paper, the quasithermodynamic fluctuation theory of a model system of a large number of oscillators is extended to statistical thermodynamics based on the idea of perceiving the fluctuations of intensive variables as the fluctuations of specific extensive ones in a "thermodynamically dual" system. The extension is motivated by the symmetry of the problem in the context of an analogy with quantum mechanics, which is stated in terms of a generalized Pauli problem for the thermodynamic fluctuations. The doubled Boltzmann constant divided by the number of particles plays a similar role as the Planck constant.
    • File Description:
      pdf
    • Relation:
      info:eu-repo/semantics/altIdentifier/isi/000328487400017
    • الدخول الالكتروني :
      https://hdl.handle.net/10067/1137210151162165141
      https://repository.uantwerpen.be/docman/irua/3250d8/6635.pdf
    • Rights:
      info:eu-repo/semantics/openAccess
    • الرقم المعرف:
      edsbas.FCD8F072