نبذة مختصرة : International audience ; Layered melilite-type gallates of general formula RE 1+x AE 1-x Ga 3 O 7+x/2 are of interest for their ability to host mobile interstitial oxide ions in [Ga 3 O 7+x ] layers. The crystal structure of Ca 5 Ga 6 O 14 is closely related to melilite, with [Ga 3 O 7 ] layers stacked in a more complex way to accommodate an additional 0.5 interlayer cations per formula unit, suggesting the potential for similar oxide ion conduction behaviour. We used a computational approach to identify the most promising routes to interstitial oxide incorporation into Ca 5 Ga 6 O 14 , leading to an experimental investigation of the system Ca 5-x Ga 6 O 14+x/2 . Single-phase materials were obtained in the range 0 ≤ x ≤ 0.25 by solid state reactions, producing an ~40× increase in ionic conductivity at 800°C. This limited compositional range presents a challenge for characterisation of the charge-compensating defects. The La substituents were observed directly by X-ray diffraction and STEM-EDX, and a combination of different structural characterization techniques and DFT calculations indicated the presence of interstitial oxide ions indirectly, explaining the conductivity response. As higher carrier concentrations (x > 0.25) are apparently inaccessible in this system, we conclude that its potential as a useful oxide ion conductor is more limited than that of established melilite materials such as La 1+x Ca 1-x Ga 2 O 7+x/2
Processing Request
No Comments.