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Comparative analysis of analytical methods for the quantification of sulfates in reconstituted soil matrices: Effect of soil texture and interfering species

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  • معلومة اضافية
    • Contributors:
      Chimie Analytique et Réactivité Moléculaire En Normandie (Institut CARMeN); Université de Caen Normandie (UNICAEN); Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN); Normandie Université (NU)-Université de Rouen Normandie (UNIROUEN); Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie); Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS); ESCOM - Ecole Supérieure de Chimie Organique et Minérale (ESCOM); Transformations Intégrées de la Matière Renouvelable (TIMR); Université de Technologie de Compiègne (UTC)-Université de Technologie de Compiègne (UTC); TELLUX; Equipe Apprentissage (LITIS - App); Laboratoire d'Informatique, du Traitement de l'Information et des Systèmes (LITIS); Université Le Havre Normandie (ULH); Normandie Université (NU)-Normandie Université (NU)-Université de Rouen Normandie (UNIROUEN); Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Université Le Havre Normandie (ULH); Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)
    • بيانات النشر:
      CCSD
      Elsevier
    • الموضوع:
      2025
    • Collection:
      Normandie Université: HAL
    • نبذة مختصرة :
      International audience ; This article studies the effect of various soil textures on sulfate determination and compares the performance of ion chromatography and the turbidimetric method for quantifying sulfates in reconstituted soil matrices. The comparison is conducted under both interference-free conditions and in the presence of interferences, such as chlorides and fluorides. These interferences caused significant overestimations of theoretical sulfate concentrations when using the standardized turbidimetric method. For instance, at a theoretical sulfate concentration of 1000 mg/kg, the result obtained through the turbidimetric method was 12085.5 mg/kg in the presence of chlorides, while the result obtained through ion chromatography was 915.5 mg/kg. An alternative method relying on hyperspectral imaging is also presented for direct sulfate analysis in soil without the need for extraction. Hyperspectral analyses proved to enable rapid analysis and accurate prediction of sulfate concentrations in soil samples, with an R2 score of 0.87 in the absence of interferences and an R2 score of 0.9 in the presence of chlorides.
    • الرقم المعرف:
      10.1016/j.eti.2025.104182
    • الدخول الالكتروني :
      https://hal.science/hal-05271180
      https://hal.science/hal-05271180v1/document
      https://hal.science/hal-05271180v1/file/main.pdf
      https://doi.org/10.1016/j.eti.2025.104182
    • Rights:
      info:eu-repo/semantics/OpenAccess
    • الرقم المعرف:
      edsbas.98C747E7