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Highly Efficient Biobased Synthesis of Acrylic Acid.

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  • المؤلفون: Hermens JGH;Hermens JGH; Jensma A; Jensma A; Feringa BL; Feringa BL
  • المصدر:
    Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2022 Jan 21; Vol. 61 (4), pp. e202112618. Date of Electronic Publication: 2021 Dec 13.
  • نوع النشر :
    Journal Article; Research Support, Non-U.S. Gov't
  • اللغة:
    English
  • معلومة اضافية
    • المصدر:
      Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: PubMed not MEDLINE; MEDLINE
    • بيانات النشر:
      Publication: <2004-> : Weinheim : Wiley-VCH
      Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962-
    • نبذة مختصرة :
      Petrochemical based polymers, paints and coatings are cornerstones of modern industry but our future sustainable society demands greener processes and renewable feedstock materials. A challenge is to access platform monomers from biomass resources while integrating the principles of green chemistry in their chemical synthesis. We present a synthesis route starting from biomass-derived furfural towards the commonly used monomers maleic anhydride and acrylic acid, implementing environmentally benign photooxygenation, aerobic oxidation and ethenolysis reactions. Maleic anhydride and acrylic acid, transformed into sodium acrylate, were isolated in yields of 85 % (2 steps) and 81 % (4 steps), respectively. With minimal waste and high atom efficiency, this biobased route provides a viable alternative to access key monomers.
      (© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)
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    • Grant Information:
      736.000.000 Nederlandse Organisatie voor Wetenschappelijk Onderzoek
    • Contributed Indexing:
      Keywords: acrylic acid; biobased polymers; furfural; maleic anhydride; sustainability
    • الموضوع:
      Date Created: 20211116 Date Completed: 20220207 Latest Revision: 20240901
    • الموضوع:
      20250114
    • الرقم المعرف:
      PMC9299676
    • الرقم المعرف:
      10.1002/anie.202112618
    • الرقم المعرف:
      34783426