نبذة مختصرة : Silver-containing oxidizers are of interest as biocidal components in energetic application such as thermites due to their biocidal agent delivery. In this study, AgFeO2, was evaluated as an oxidizer in aluminum-based thermite system. This novel oxidizer AgFeO2 particles were prepared via a wet-chemistry method and its structure, morphologies and thermal behavior were investigated using X-ray diffraction, scanning electron microscopy, thermogravimetric analysis and differential scanning calorimetry, and time-resolved temperature-jump time-of-flight mass spectrometry. The results indicate the decomposition pathways of AgFeO2 vary with heating rates from a two-step at low heating rate to a single step at high heating rate. Ignition of Al/AgFeO2 occurs at a temperature just above the oxygen release temperature that is very similar to Al/Fe2O3 and Al/CuO. However, with a pressurization rate three times of Al/CuO, Al/AgFeO2 yields a comparable result as to Al/hollow-CuO or Al/KClO4/CuO, with a simpler preparation method. The post combustion products demonstrated that the Al/AgFeO2 thermite reaction produces a fine dispersion of elemental nanosized silver particles which coats the larger alumina particles and is thus bioavailable.
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