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Slot-die coating of electron transport layers for perovskite solar cells using water and butanol-based tin oxide dispersions

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  • معلومة اضافية
    • Publisher Information:
      Uppsala universitet, Fysikalisk kemi CSIC, Catalan Inst Nanosci & Nanotechnol ICN2, Bldg ICN2,Campus UAB, E-08193 Barcelona, Spain.;Barcelona Inst Sci & Technol BIST, Bldg ICN2, Campus UAB, E-08193 Barcelona, Spain. CSIC, Catalan Inst Nanosci & Nanotechnol ICN2, Bldg ICN2,Campus UAB, E-08193 Barcelona, Spain.;Barcelona Inst Sci & Technol BIST, Bldg ICN2, Campus UAB, E-08193 Barcelona, Spain. 2024
    • نبذة مختصرة :
      Lead halide perovskite photovoltaics have shown an impressive efficiency increase over the past decade. Making this technology industrially viable requires precise optimization of every single deposition step. Here we used slot-die coating, a promising scalable deposition technique to enable large scale deposition. We demonstrate the challenges in developing high-quality slot-die coated tin oxide (SnO2) films, suited as electron selective layers in perovskite solar cells. We studied the film quality of two commercially available colloidal SnO2 dispersions by controlling pump rate, coating speed and temperature of the indium tin oxide substrates (ITO). The water-based dispersion was more difficult to control, but resulted in better perovskite solar cell performance than the butanol-based dispersion. Hysteresis in J–V curves from the water-based tin oxide dispersion was reduced by potassium fluoride addition. A maximum power conversion efficiency of 17.5% was achieved for MAPbI3-based solar cells by careful optimization of the deposition parameters.
    • الموضوع:
    • الرقم المعرف:
      10.1039.d4ma00351a
    • Availability:
      Open access content. Open access content
      info:eu-repo/semantics/openAccess
    • Note:
      application/pdf
      English
    • Other Numbers:
      UPE oai:DiVA.org:uu-541399
      0000-0003-2046-1229
      0000-0002-6619-4798
      0000-0002-3393-7436
      0000-0003-2134-4702
      0000-0002-8249-1469
      doi:10.1039/d4ma00351a
      ISI:001204137100001
      1481650422
    • Contributing Source:
      UPPSALA UNIV LIBR
      From OAIster®, provided by the OCLC Cooperative.
    • الرقم المعرف:
      edsoai.on1481650422
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