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Ir-Catalyzed ortho-C-H Borylation of Aromatic C(sp2)-H Bonds of Carbocyclic Compounds Assisted by N-Bearing Directing Groups

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  • معلومة اضافية
    • بيانات النشر:
      MDPI AG, 2024.
    • الموضوع:
      2024
    • Collection:
      LCC:Chemistry
    • نبذة مختصرة :
      C-H borylation is a powerful strategy for the construction of C-B bonds due to the synthetic versatility of C-B bonds. Various transition metals affect the powerful functionalization of C-H bonds, of which Ir is the most common. Substrate-directed methods have enabled directed Ir-catalyzed C-H borylation at the ortho position. Amongst the powerful directing groups in Ir-catalyzed C-H borylation are N-containing carbocyclic systems. This review covers substrate-directed Ir-catalyzed ortho-C-H borylation of aromatic C(sp2)-H bonds in N-containing carbocyclic compounds, such as anilines, amides, benzyl amines, hydrazones, and triazines.
    • File Description:
      electronic resource
    • ISSN:
      2624-781X
    • Relation:
      https://www.mdpi.com/2624-781X/5/2/16; https://doaj.org/toc/2624-781X
    • الرقم المعرف:
      10.3390/reactions5020016
    • الرقم المعرف:
      edsdoj.2e7eb199112b48cf80952badab764f0a