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Tf 2 O/DMSO-Promoted P–O and P–S Bond Formation: A Scalable Synthesis of Multifarious Organophosphinates and Thiophosphates

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  • معلومة اضافية
    • الموضوع:
      2021
    • Collection:
      Smithsonian Institution: Digital Repository
    • نبذة مختصرة :
      A Tf 2 O/DMSO-based system for the dehydrogenative coupling of a wide range of alcohols, phenols, thiols, and thiophenols with diverse phosphorus reagents has been developed. This metal- and strong-oxidant-free strategy provides a facile approach to a great variety of organophosphinates and thiophosphates. The simple reaction system, good functional-group tolerance, and broad substrate scope enable the application of this method to the modification of natural products and the direct synthesis of bioactive molecules and flame retardants.
    • Relation:
      https://figshare.com/articles/journal_contribution/Tf_sub_2_sub_O_DMSO-Promoted_P_O_and_P_S_Bond_Formation_A_Scalable_Synthesis_of_Multifarious_Organophosphinates_and_Thiophosphates/14102536
    • الرقم المعرف:
      10.1021/acs.orglett.0c04127.s002
    • الدخول الالكتروني :
      https://doi.org/10.1021/acs.orglett.0c04127.s002
    • Rights:
      CC BY-NC 4.0
    • الرقم المعرف:
      edsbas.FD8F8966