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Synthesis of 3-benzylisoquinolines by domino imination/cycloisomerisation of 2-propargylbenzaldehydes

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اقرأ أكثر حفظ في قائمتي
  • معلومة اضافية
    • Contributors:
      M. Dell'Acqua; V. Pirovano; G. Confalonieri; A. Arcadi; E. Rossi; G. Abbiati
    • بيانات النشر:
      Royal Society of Chemistry
    • الموضوع:
      2014
    • Collection:
      The University of Milan: Archivio Istituzionale della Ricerca (AIR)
    • نبذة مختصرة :
      An easy entry to uncommon 2-propargylbenzaldehydes was developed. 2-propargylbenzaldehydes demonstrated to be suitable building blocks for the synthesis of 3-benzyl isoquinolines by microwave promoted domino imination/cycloisomerisation in the presence of ammonium acetate. A small library of 3-benzyl isoquinolines was obtained in good yields under mild reaction conditions. Two alternative plausible reaction mechanisms are proposed.
    • Relation:
      info:eu-repo/semantics/altIdentifier/pmid/25237794; info:eu-repo/semantics/altIdentifier/wos/WOS:000342992400018; volume:12; issue:40; firstpage:8019; lastpage:8030; numberofpages:12; journal:ORGANIC & BIOMOLECULAR CHEMISTRY; http://hdl.handle.net/2434/238782; info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-84907486052
    • الرقم المعرف:
      10.1039/C4OB01583E
    • الدخول الالكتروني :
      http://hdl.handle.net/2434/238782
      https://doi.org/10.1039/C4OB01583E
    • Rights:
      info:eu-repo/semantics/openAccess
    • الرقم المعرف:
      edsbas.F9F6ABE9