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Enzymatic resolution of 1,1-dimethoxybut-3-en-2-ol and 1,1-dimethoxypent-4-en-2-ol, alpha-hydroxyaldehyde precursors for aldol-type reactions

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  • معلومة اضافية
    • Contributors:
      Synthèse et étude de systèmes à intêret biologique (SEESIB); Université Blaise Pascal - Clermont-Ferrand 2 (UBP)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)
    • بيانات النشر:
      HAL CCSD
      Elsevier
    • الموضوع:
      2005
    • Collection:
      HAL Clermont Auvergne (Université Blaise Pascal Clermont-Ferrand / Université d'Auvergne)
    • نبذة مختصرة :
      Hydroxyacetals 2 and 3 were resolved by acylation with vinyl acetate in the presence of lipases in organic media. The reverse reaction, the enzymatic hydrolysis of the corresponding acetates, was also highly stereoselective and provided the opposite enantiomers
    • Relation:
      hal-00125718; https://hal.science/hal-00125718; https://hal.science/hal-00125718/document; https://hal.science/hal-00125718/file/TA2005-2.pdf
    • الرقم المعرف:
      10.1016/j.tetasy.2005.05.013
    • Rights:
      info:eu-repo/semantics/OpenAccess
    • الرقم المعرف:
      edsbas.E1920A92