نبذة مختصرة : Fluorohydrogenate ionic liquids of quaternary phosphonium cations, tri-n-butylmethylphosphonium (P4441) fluorohydrogenate, tetra-n-butylphosphonium (P4444) fluorohydrogenate, and tri-n-butyl-n-octylphosphonium (P4448) fluorohydrogenate, have been synthesized by the metatheses of anhydrous hydrogen fluoride and the corresponding phosphonium chloride precursors. All the obtained salts have melting points below room-temperature with a vacuum-stable composition of P₄₄₄ₘ(FH)₂.₃F (m = 1, 4, and 8) and were characterized by density, conductivity, and viscosity measurements. Linear sweep voltammetry with a glassy carbon working electrode shows that the P₄₄₄ₘ(FH)₂.₃Fs have wide electrochemical windows exceeding 5.2 V. In particular, P₄₄₄₁(FH)₂.₃F has an electrochemical window of 6.0 V, which is the widest among fluorohydrogenate ionic liquids reported to date. The thermal stability of these ionic liquids is also improved compared to the salts of N-heterocyclic ammonium cations.
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