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Improved Performance of a Europium-based Metal-Organic Framework for Cyanosilylation of Demanding Ketones

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  • معلومة اضافية
    • بيانات النشر:
      Wiley
    • الموضوع:
      2022
    • Collection:
      DIGIBUG: Repositorio Institucional de la Universidad de Granada
    • نبذة مختصرة :
      Solvothermally promoted assembly of the multifunctional 3-amino-4-hydroxybenzoic acid ligand with the corresponding Eu salt gives rise to the formation of a porous metal-organic framework with the general formula {[Eu5L6(OH)3(H2O)3] ⋅ 5DMF}n (1) that has been tested as heterogeneous catalyst for the cyanosilylation of a broad scope of ketones in solvent-free conditions, using the lowest catalyst loading of 0.5 mol% ever reported, and exhibiting no leak and high recyclability. ; State Research Agency. Grant Numbers: CTQ2017-84334-R, PGC2018-102052-B−C21 ; Spanish Ministry of Science, Innovation and Universities ; European Union (European Regional Development Fund – ERDF) ; Junta de Andalucía. Grant Numbers: 102 C2000004, CV20-78799, P20_01041, UAL-FEDER UAL2020-AGR−B1781, FQM-376, FQM-394 ; Gobierno de España. Grant Numbers: MCIN/AEI/10.13039/501100011033/Unión Europea “Next GenerationEU”/PRTR, PDC2021-121248-I00, PLEC2021-007774 ; Government of the Basque Country ; Juan de la Cierva Incorporación. Grant Number: IJC2019-038894-I ; Hipatia fellowship (University of Almería, grant no. HIPATIA2021 04).
    • Relation:
      https://hdl.handle.net/10481/97676
    • الرقم المعرف:
      10.1002/cctc.202200967
    • الدخول الالكتروني :
      https://hdl.handle.net/10481/97676
      https://doi.org/10.1002/cctc.202200967
    • Rights:
      Atribución 4.0 Internacional ; http://creativecommons.org/licenses/by/4.0/ ; open access
    • الرقم المعرف:
      edsbas.CFABD2AC