Measurement of methane emissions from confined sources using the inverse dispersion method

Greenhouse gas (GHG) emissions are reported in annual national inventories. Globally, the main anthropogenic sources of methane (CH4) are fossil fuel burning, agriculture, landfills, and waste management. The main source of CH4 from agriculture is enteric fermentation in the digestive tract of ruminants and a minor source are emissions from manure management. In 2019, the Swiss Federal council decided that Switzerland must reduce its GHG emission to net-zero until 2050. To reach this goal, the agricultural sector is obliged to contribute to the emission reduction. However, emissions from the agriculture and waste sector imply large uncertainties as, among other reasons, the availability of data based on real-world studies is limited. Several investigations showed that measurements from laboratory- or pilot-scale experiments do often not comply with real-world conditions. For studies under real-world conditions, different measurement approaches are available. One of the most promising methods is the inverse dispersion method (IDM) that was applied in this thesis to measure CH 4 emissions from livestock production and the waste management sector in order to evaluate the method for complex source configurations and to specify emission factors of these sources. For the IDM, a backward Lagrangian stochastic (bLS) model in combination with concentration measurements up- and downwind of the source using open-path tunable diode laser spectrometers (GasFinders) were employed. GasFinders are simple to use, flexible in their application, and relatively cost-effective measuring devices. However, several challenges were faced and overcome throughout the thesis. The precision of the employed GasFinder model was about 10 times lower than the manufacturer stated, which necessitated adaptation in the measurement setup. Additionally, an intercomparison before or after each measurement campaign was necessary to correct the offset and span between the employed GasFinders. In the first two studies presented in this thesis, ...