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Electrocatalytic behavior of tetrathiafulvalene (TTF) and extended tetrathiafulvalene (exTTF) [FeFe] hydrogenase mimics

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  • معلومة اضافية
    • Contributors:
      UAM. Departamento de Química Inorgánica
    • بيانات النشر:
      American Chemical Society
    • الموضوع:
      2023
    • Collection:
      Universidad Autónoma de Madrid (UAM): Biblos-e Archivo
    • نبذة مختصرة :
      TTF- and exTTF-containing [(μ-S2)Fe2(CO)6] complexes have been prepared by the photochemical reaction of TTF or exTTF and [(μ-S2)Fe2(CO)6]. These complexes are able to interact with PAHs. In the absence of air and in acid media an electrocatalytic dihydrogen evolution reaction (HER) occurs, similarly to analogous [(μ-S2)Fe2(CO)6] complexes. However, in the presence of air, the TTF and exTTF organic moieties strongly influence the electrochemistry of these systems. The reported data may be valuable in the design of [FeFe] hydrogenase mimics able to combine the HER properties of the [FeFe] cores with the unique TTF properties
    • File Description:
      application/pdf
    • ISBN:
      978-2-01-910842-7
      2-01-910842-9
    • Relation:
      ACS Organic and Inorganic Au; https://doi.org/10.1021/acsorginorgau.1c00011; Gobierno de España. PID2019-108429RB-I00; ACS Organic and Inorganic Au 2.1 (2022): 23-33; 2694-247X (online); http://hdl.handle.net/10486/706923; 23; 33
    • الرقم المعرف:
      10.1021/acsorginorgau.1c00011
    • الدخول الالكتروني :
      http://hdl.handle.net/10486/706923
      https://doi.org/10.1021/acsorginorgau.1c00011
    • Rights:
      © 2021 The Authors ; Reconocimiento ; openAccess
    • الرقم المعرف:
      edsbas.9DF9B822