WASP-121 b’s transmission spectrum observed with JWST/NIRSpec G395H reveals thermal dissociation and SiO in the atmosphere

This is the author accepted manuscript ; This work is based on observations made with the NASA/ESA/CSAJWST. The data were obtained from the Mikulski Archive for Space Telescopes at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS5-03127 for JWST. The specific observations analyzed can be accessed via 10.17909/6qnn-6j23. ; WASP-121b has been established as a benchmark Ultra-Hot Jupiter, serving as a laboratory for the atmospheric chemistry and dynamics of strongly irradiated extrasolar gas giants. Here, we present andanalyze WASP-121b’s transmission spectrum observed with NIRSpec G395H on board the James Webb Space Telescope (JWST) and find evidence for the thermal dissociation of H2O and H2 on the planet’s permanent day side. Additionally, we detect SiO at a statistical significance of 5.2σ which is compatible with chemical equilibrium in the atmosphere. Constraining the abundance of SiO and abundance ratios between Silicon and volatile atoms in WASP-121b’s atmosphere could help discriminate between possible migration histories of the planet. The three-dimensional nature of thermal dissociation on WASP-121b’s day side and recombination on its night side, however, poses a challenge to constrain molecular abundances and elemental abundance ratios from the transmission spectrum. To account for this, we implemented an atmospheric model in the NEMESIS framework that splits the planet’s atmosphere into day side and night side. A retrieval applying our atmospheric model to WASP-121b’s transmission spectrum favors a higher H2O abundance on the night side than on the day side, demonstrating the impact of hemispheric heterogeneity when attempting to constrain WASP-121b’s bulk H2O inventory. ; Science and Technology Facilities Council (STFC) ; UK Research and Innovation ; Leverhulme Trust