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Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates

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  • معلومة اضافية
    • Contributors:
      Natural Science Foundation of Henan Province; Education Department of Henan Province; Henan Agricultural University
    • بيانات النشر:
      Frontiers Media SA
    • الموضوع:
      2022
    • Collection:
      Frontiers (Publisher - via CrossRef)
    • نبذة مختصرة :
      We report herein a facile Hiyama cross-coupling reaction of arylsilanes with thiuram reagents (tetraalkylthiuram disulfides or tetraalkylthiuram monosulfide) enabled by copper fluoride. Compared to our previous work, this protocol is an alternative protocol for the generation of S-aryl dithiocarbamates. It features low toxic and readily available substrates, cost-effective promoter, easy performance, and provides good yields.
    • الرقم المعرف:
      10.3389/fchem.2022.867806
    • الرقم المعرف:
      10.3389/fchem.2022.867806/full
    • Rights:
      https://creativecommons.org/licenses/by/4.0/
    • الرقم المعرف:
      edsbas.9795169F