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Green and efficient recovery of valuable metals from spent lithium-ion batteries using molasses: Parametric optimization and performance evaluation.

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  • معلومة اضافية
    • بيانات النشر:
      Elsevier
    • الموضوع:
      2023
    • Collection:
      Brunel University London: Brunel University Research Archive (BURA)
    • نبذة مختصرة :
      Supplementary data to this article can be found online at: https://doi.org/10.1016/j.hydromet.2023.106168. ; In this study, a green and efficient leaching system utilizing methanesulfonic acid (MSA) and sugarcane molasses is investigated, and conditions optimized using response surface methodology (RSM). Results show that molasses is capable of reducing the oxidation state thus facilitating the leaching of the transition metals and lithium. The dissolution rate of the metals in molasses-methanesulfonic acid media is observed to be fast and temperature dependent. >98% of all the metals can be dissolved under the optimized leaching condition of 2 M MSA, reductant dosage of 0.408 g (molasses)/g (cathode material) on a wet molasses (18.5% moisture) and dry cathode material basis, solid-liquid ratio of 50 g/L, 90 °C and 60 min. The proposed system provides an efficient waste-to-wealth approach that utilizes an agro-industrial by-product to recover hazardous metals present in spent LIBs.
    • File Description:
      Print-Electronic
    • ISSN:
      0304-386X
      1879-1158
    • Relation:
      Hydrometallurgy; ORCiD: Emenike Okonkwo orcid:0000-0001-8841-693X; ORCiD: Greg Wheatley orcid:0000-0001-9416-3908; ORCiD: Yinghe He orcid:0000-0003-4252-5414; 106168; Okonkwo, E.G. et al. (2023) ‘Green and efficient recovery of valuable metals from spent lithium-ion batteries using molasses: Parametric optimization and performance evaluation’, Hydrometallurgy, 222, pp. 1 - 10. doi:10.1016/j.hydromet.2023.106168.; https://bura.brunel.ac.uk/handle/2438/28327; https://doi.org/10.1016/j.hydromet.2023.106168
    • الرقم المعرف:
      10.1016/j.hydromet.2023.106168
    • Rights:
      Crown Copyright ? The Authors © 2023 Published by Elsevier B.V. This is an open access article under the CCBY license (https://creativecommons.org/licenses/by/4.0/). Creative Commons This is an open access article distributed under the terms of the Creative Commons CC-BY license, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. You are not required to obtain permission to reuse this article. ; https://creativecommons.org/licenses/by/4.0/
    • الرقم المعرف:
      edsbas.95FD3E8C