Item request has been placed! ×
Item request cannot be made. ×
loading  Processing Request

Submillimeter-wave spectroscopy of and interstellar search for thioacetaldehyde

Item request has been placed! ×
Item request cannot be made. ×
loading   Processing Request
  • معلومة اضافية
    • Contributors:
      Laboratoire de Physique des Lasers, Atomes et Molécules - UMR 8523 (PhLAM); Université de Lille-Centre National de la Recherche Scientifique (CNRS); Physique Moléculaire aux Interfaces (PMI); Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université de Lille-Centre National de la Recherche Scientifique (CNRS); National Academy of Sciences of Ukraine = Національна академія наук України = Académie nationale des sciences d'Ukraine (NASU / НАН України); Kharkov National University; National Radio Astronomy Observatory (NRAO); Max-Planck-Institut für Radioastronomie (MPIFR); Institut des Sciences Chimiques de Rennes (ISCR); Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes); Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS); Programme National "Physique et Chimie du Milieu Interstellaire"; (PCMI) of CNRS/INSU with INC/INP; CNES Centre National D'Etudes Spatiales; NASA through Hubble Fellowship - Space Telescope Science Institute HST-HF2-51396; NASA National Aeronautics and Space Administration (NASA) NAS5-26555; Centre National d'Etudes Spatiales (CNES) Centre National D'etudes Spatiales; Volkswagen foundation Volkswagen; Science and Technology Center in the Ukraine P686; Deutsche Forschungsgemeinschaft (DFG) German Research Foundation (DFG) 184018867, 956; CEA French Atomic Energy Commission
    • بيانات النشر:
      HAL CCSD
      Elsevier
    • الموضوع:
      2020
    • Collection:
      Université de Rennes 1: Publications scientifiques (HAL)
    • نبذة مختصرة :
      International audience ; We present a new study of the millimeter and submillimeter wave spectra of the thioacetaldehyde molecule, CH3CHS, a sulfur-bearing analog of the ubiquitous interstellar molecule acetaldehyde (CH3CHO). Here, we present a laboratory investigation aimed at determining accurate spectroscopic parameters for CH3CHS to enable astronomical searches for this molecule using radio telescopes at millimeter and submillimeter wavelengths. New laboratory measurements have been carried out between 150 and 660 GHz using the spectrometer of PhLAM in Lille (France). Rotational transitions up to J = 60 were assigned in the ground, first, and second excited torsional states of thioacetaldehyde and fit using the RAM Hamiltonian model. The final fit includes 62 parameters to give an overall weighted root-mean-square deviation of 0.9. On the basis of our spectroscopic results, CH3CHS was searched for, but not detected, in data from the Atacama Large Millimeter/submillimeter Array (ALMA) between 84 GHz and 114 GHz toward the hot molecular core Sgr B2(N2). The non-detection implies that thioacetaldehyde is at least 90 times less abundant than acetaldehyde in this source. We also searched for but found no evidence of thioacetaldehyde in a number of prestellar and protostellar sources targeted by the Astrochemical Surveys at IRAM (ASAI) Large Program in nearby low-mass star forming regions.
    • Relation:
      hal-02928605; https://hal.science/hal-02928605; https://hal.science/hal-02928605/document; https://hal.science/hal-02928605/file/Margul%C3%A8s%20et%20al-2020-Submillimeter-wave%20spectroscopy%20of%20and%20interstellar%20search%20for%20thioacetaldehyde.pdf
    • الرقم المعرف:
      10.1016/j.jms.2020.111304
    • الدخول الالكتروني :
      https://hal.science/hal-02928605
      https://hal.science/hal-02928605/document
      https://hal.science/hal-02928605/file/Margul%C3%A8s%20et%20al-2020-Submillimeter-wave%20spectroscopy%20of%20and%20interstellar%20search%20for%20thioacetaldehyde.pdf
      https://doi.org/10.1016/j.jms.2020.111304
    • Rights:
      info:eu-repo/semantics/OpenAccess
    • الرقم المعرف:
      edsbas.845620B1