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Reduction and Rearrangement of a Boron(I) Carbonyl Complex

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  • معلومة اضافية
    • بيانات النشر:
      Wiley
    • الموضوع:
      2021
    • Collection:
      University of Kent: KAR - Kent Academic Repository
    • نبذة مختصرة :
      The one-electron reduction of a cyclic (alkyl)(amino)carbene (CAAC)-stabilized arylborylene carbonyl complex yields a dimeric borylketyl radical anion, resulting from an intramolecular aryl migration to the CO carbon atom. Computational analyses support the existence of a [(CAAC)B(CO)Ar].− radical anion intermediate. Further reduction leads to a highly nucleophilic dianionic (boraneylidene)methanolate.
    • File Description:
      application/pdf
    • Relation:
      https://kar.kent.ac.uk/96289/1/Angew%20Chem%20Int%20Ed%20-%202020%20-%20Rang%20-%20Reduction%20and%20Rearrangement%20of%20a%20Boron%20I%20%20Carbonyl%20Complex.pdf; Rang, Maximilian, Fantuzzi, Felipe, Arrowsmith, Merle, Krummenacher, Ivo, Beck, Eva, Witte, Robert, Matler, Alexander, Rempel, Anna, Bischof, Tobias, Radacki, Krzysztof, and others. Engels, Bernd, and Braunschweig, Holger (hide) (2021) Reduction and Rearrangement of a Boron(I) Carbonyl Complex. Angewandte Chemie International Edition, 60 (6). pp. 2963-2968. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202014167 ) (KAR id:96289 )
    • الرقم المعرف:
      10.1002/anie.202014167
    • الدخول الالكتروني :
      https://kar.kent.ac.uk/96289/
      https://doi.org/10.1002/anie.202014167
    • Rights:
      cc_by
    • الرقم المعرف:
      edsbas.789CE091