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Hybrid photo-induced copolymerization of ring-strained and vinyl monomers utilizing metal-free ring-opening metathesis polymerization conditions

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  • معلومة اضافية
    • بيانات النشر:
      American Chemical Society
    • الموضوع:
      2019
    • Collection:
      Queensland University of Technology: QUT ePrints
    • نبذة مختصرة :
      We introduce the hybrid copolymerization of two disparate monomer classes (vinyl monomers and ring-strained cyclic olefins) via living photopolymerization. The living character of the polymerization technique (metal-free photo-ROMP) is demonstrated by consecutive chain-extensions. Further, we propose a mechanism for the copolymerization and analyze the copolymer structure in detail by high-resolution mass spectrometry.
    • File Description:
      application/pdf
    • Relation:
      https://eprints.qut.edu.au/135894/1/Hybrid_photo_induced_copolymerization_of_ring_strained_and_vinyl_monomers_utilizing_metal_free_ring_opening_metathesis_polymerization_conditions.pdf; Krappitz, Tim, Jovic, Kristina, Feist, Florian, Frisch, Hendrik, Rigoglioso, Vincent P., Blinco, James P., Boydston, Andrew J., & Barner-Kowollik, Christopher (2019) Hybrid photo-induced copolymerization of ring-strained and vinyl monomers utilizing metal-free ring-opening metathesis polymerization conditions. Journal of the American Chemical Society, 141(42), pp. 16605-16609.; https://eprints.qut.edu.au/135894/; Institute for Future Environments; Science & Engineering Faculty; Division of Research and Innovation
    • Rights:
      free_to_read ; http://creativecommons.org/licenses/by-nc/4.0/ ; Consult author(s) regarding copyright matters ; This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au
    • الرقم المعرف:
      edsbas.760CB56E