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From K-6[Re6-xMoxS8(CN)(5)] Solid Solution to Individual Cluster Complexes: Separation and Investigation of [Re4Mo2S8(CN)(6)](n-) and [Re3Mo3S8(CN)(6)](n-) Heterometallic Clusters

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اقرأ أكثر حفظ في قائمتي
  • معلومة اضافية
    • Contributors:
      Russian Academy of Sciences Moscow (RAS); Nikolaev Institute of Inorganic Chemistry Novosibirsk (NIC); Siberian Branch of the Russian Academy of Sciences (SB RAS); Institut des Sciences Chimiques de Rennes (ISCR); Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes); Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS); Institut Jean Lamour (IJL); Institut de Chimie - CNRS Chimie (INC-CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS); Russian Science Foundation 22-73-10181
    • بيانات النشر:
      HAL CCSD
    • الموضوع:
      2023
    • Collection:
      Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe)
    • نبذة مختصرة :
      International audience ; A series of new cluster compounds with {Re4Mo2S8} and {Re3Mo3S8} cores has been obtained and investigated. The clusters with different Re/Mo ratios were isolated as individual compounds, which made it possible to study their spectroscopic and electrochemical properties. The geometry of the new clusters was studied using a combination of X-ray diffraction analysis, XAS and quantum chemical DFT calculations. It was shown that the properties of the new clusters, such as the number and position of electrochemical transitions, electronic structure and change in geometry with a change in charge, are similar to the properties of clusters based on the {Re4Mo2Se8} and {Re3Mo3Se8} cores described earlier.
    • Relation:
      info:eu-repo/semantics/altIdentifier/pmid/37570845; hal-04193503; https://hal.science/hal-04193503; https://hal.science/hal-04193503/document; https://hal.science/hal-04193503/file/molecules-28-05875.pdf; PUBMED: 37570845
    • الرقم المعرف:
      10.3390/molecules28155875
    • Rights:
      http://creativecommons.org/licenses/by/ ; info:eu-repo/semantics/OpenAccess
    • الرقم المعرف:
      edsbas.65C05417