نبذة مختصرة : Polyanion-type Li 2 MnSiO 4 is considered to be a potential lithium storage material due to its high theoretical capacity, low cost, nontoxicity, and good thermal stability. Unfortunately, pure Li 2 MnSiO 4 has poor conductivity and diffusion rate of Li + , which hinders its wide application in energy storage. In this study, Li 2 MnSiO 4 with inverse opal structure is synthesized by simple sol–gel method, and monodisperse polystyrene microspheres (PS) with uniform and controllable size are prepared by soap-free emulsion. Additionally, Li 2 MnSiO 4 material with a large specific surface area and mesoporous structure is synthesized by using PS as a template. Specifically, after adding 4 wt% of the PS template, the initial discharge specific capacity of the synthesized Li 2 MnSiO 4 material is 109.9 mAh·g −1 at 0.1 C. Compared with pure Li 2 MnSiO 4 , the electrochemical performance of the material synthesized by this process has been significantly improved, which is attributed to the mesoporous structure and large specific surface area that improve the conductivity. Hence, the Li 2 MnSiO 4 cathode material synthesized with PS as a template is expected to become an advanced positive material in lithium energy storage.
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