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The reduction of specific disulfides with titanium(III) chloride

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اقرأ أكثر حفظ في قائمتي
  • المؤلفون: Akers, Hugh A.; Vang, Meng C.; Updike, Tracie D.
  • المصدر:
    Canadian Journal of Chemistry ; volume 65, issue 6, page 1364-1366 ; ISSN 0008-4042 1480-3291
  • نوع التسجيلة:
    article in journal/newspaper
  • اللغة:
    French
  • معلومة اضافية
    • بيانات النشر:
      Canadian Science Publishing
    • الموضوع:
      1987
    • نبذة مختصرة :
      The reaction between titanium(III) chloride and disulfides was investigated. Aryl and alkyl disulfides did not react while heterocyclic aromatic disulfides with a nitrogen α to the sulfur were reduced to the corresponding thiols. Products were identified and characterized by nuclear magnetic resonance and infrared spectra, and melting point comparisons with authentic compounds. The reductions occurred only in the presence of citrate and were found to require 2 moles of titanium(III) per mole of disulfide.
    • الرقم المعرف:
      10.1139/v87-230
    • Rights:
      http://www.nrcresearchpress.com/page/about/CorporateTextAndDataMining
    • الرقم المعرف:
      edsbas.455D050C