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Photochemically Driven Nickel‐Catalyzed Carboxylative C−N Coupling: Scope and Mechanism**

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  • معلومة اضافية
    • Contributors:
      Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (ICBMS); Université Claude Bernard Lyon 1 (UCBL); Université de Lyon-Université de Lyon-École Supérieure de Chimie Physique Électronique de Lyon (CPE)-Institut National des Sciences Appliquées de Lyon (INSA Lyon); Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS); Department of Chemistry (University of Pittsburgh); University of Pittsburgh (PITT); Pennsylvania Commonwealth System of Higher Education (PCSHE)-Pennsylvania Commonwealth System of Higher Education (PCSHE); Pennsylvania Commonwealth System of Higher Education (PCSHE)
    • بيانات النشر:
      HAL CCSD
      Wiley-VCH Verlag
    • الموضوع:
      2023
    • Collection:
      HAL Lyon 1 (University Claude Bernard Lyon 1)
    • نبذة مختصرة :
      International audience ; Abstract Herein we disclosed an unprecedented photochemically driven nickel‐catalyzed carboxylative Buchwald–Hartwig amination to access a wide range of aryl carbamate derivatives. This reaction is performed under mild condition of temperature and atmospheric pressure of CO 2 starting from commercially available (hetero)aryl iodides/bromides derivatives and alkyl amines preventing the formation of hazardous and/or toxic waste. Moreover, preliminary mechanistic investigations including stochiometric experiments as well as DFT calculations allow us to shed light on the reaction mechanism.
    • Relation:
      hal-04280419; https://hal.science/hal-04280419; https://hal.science/hal-04280419/document; https://hal.science/hal-04280419/file/papier%20Ni%20CO2%20ChemRxiv.pdf
    • الرقم المعرف:
      10.1002/chem.202301271
    • الدخول الالكتروني :
      https://hal.science/hal-04280419
      https://hal.science/hal-04280419/document
      https://hal.science/hal-04280419/file/papier%20Ni%20CO2%20ChemRxiv.pdf
      https://doi.org/10.1002/chem.202301271
    • Rights:
      info:eu-repo/semantics/OpenAccess
    • الرقم المعرف:
      edsbas.1D017AA3