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Crystal structure and Hirshfeld surface analysis of (Z)-2-amino-4-(2,6-dichlorophenyl)-5-(1-hydroxyethylidene)-6-oxo-1-phenyl-1,4,5,6-tetrahydropyridine-3-carbonitrile

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  • معلومة اضافية
    • بيانات النشر:
      International Union of Crystallography, 2021.
    • الموضوع:
      2021
    • نبذة مختصرة :
      The mol­ecular conformation of the title compound is stabilized by an intra­molecular O—H⋯O hydrogen bond, forming an S(6) ring motif. Inter­molecular N—H⋯N and C—H⋯N hydrogen bonds, as well as N—H⋯π and C—H⋯π inter­actions create a three-dimensional network in the crystal.
      The mol­ecular conformation of the title compound, C20H15Cl2N3O2, is stabilized by an intra­molecular O—H⋯O hydrogen bond, forming an S(6) ring motif. The central pyridine ring is almost planar [maximum deviation = 0.074 (3) Å]. It subtends dihedral angles of 86.10 (15) and 87.17 (14)°, respectively, with the phenyl and di­chloro­phenyl rings, which are at an angle of 21.28 (15)° to each other. The =C(—OH)CH3 group is coplanar. In the crystal, mol­ecules are linked by inter­molecular N—H⋯N and C—H⋯N hydrogen bonds, and N—H⋯π and C—H⋯π inter­actions, forming a three-dimensional network. The most important contributions to the crystal packing are from H⋯H (33.1%), C⋯H/H⋯C (22.5%), Cl⋯H/H⋯Cl (14.1%), O⋯H/H⋯O (11.9%) and N⋯H/H⋯N (9.7%) inter­actions.
    • ISSN:
      2056-9890
    • Rights:
      OPEN
    • الرقم المعرف:
      edsair.doi.dedup.....f70eda2b8168f837c3bc799e288784c6