Colossal enhancement of spin-orbit coupling in weakly hydrogenated graphene

Graphene may be set to revolutionize electronics, but its small spin–orbit coupling limits its potential in spintronics. It is now shown, however, that adding hydrogen atoms can greatly enhance the magnetic properties of graphene. This then enabled the observation of the spin Hall effect, essential for controlling spin currents. Graphene’s extremely small intrinsic spin–orbit (SO) interaction1 makes the realization of many interesting phenomena such as topological/quantum spin Hall states2,3 and the spin Hall effect4 (SHE) practically impossible. Recently, it was predicted1,5,6,7 that the introduction of adatoms in graphene would enhance the SO interaction by the conversion of sp2 to sp3 bonds. However, introducing adatoms and yet keeping graphene metallic, that is, without creating electronic (Anderson) localization8, is experimentally challenging. Here, we show that the controlled addition of small amounts of covalently bonded hydrogen atoms is sufficient to induce a colossal enhancement of the SO interaction by three orders of magnitude. This results in a SHE at zero external magnetic fields at room temperature, with non-local spin signals up to 100 Ω; orders of magnitude larger than in metals9. The non-local SHE is, further, directly confirmed by Larmor spin-precession measurements. From this and the length dependence of the non-local signal we extract a spin relaxation length of ∼1 μm, a spin relaxation time of ∼ 90 ps and a SO strength of 2.5 meV.