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Three metal(II) complexes constructed using the 2-(1H-benzo[d]imidazol-2-yl)quinoline ligand

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  • معلومة اضافية
    • Contributors:
      Université frères Mentouri Constantine I (UMC); Université Larbi-Ben-Mhidi [Oum-El-Bouaghi] (OEB); Université Mohammed Seddik Benyahia [Jijel] | University of Jijel (UMSBJ); Institut des Sciences Chimiques de Rennes (ISCR); Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes); Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS); Université Mentouri Constantine [Algérie] (UMC); Université Jijel; Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1); Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes); Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)
    • بيانات النشر:
      Walter de Gruyter GmbH, 2021.
    • الموضوع:
      2021
    • نبذة مختصرة :
      2-(1H-benzo[d]imidazol-2-yl)quinoline (BQ) as ligand and three coordination compounds of formula {Zn(BQ)Cl2} (1), {Pb(BQ)Cl2} n (2) and {[Cu(BQ)2(OC(O)CH3)]OC(O)CH3 · CH3COOH} (3) have been synthesized and fully characterized. The complexes crystallize in triclinic space group P 1 ‾ $P‾{1}$ . In complexes 1 and 2, the coordination geometry is a distorted tetrahedral environment around the zinc center and a distorted sixfold coordination geometry around the lead center, respectively. In complex 3 the central Cu(II) center is in a trigonal bipyramidal coordination geometry. The Cu(II) ion is surrounded by two bidentate 2-(2′-quinolyl)benzimidazole (BQ) ligands and one coordinated acetate molecule. One further acetate anion associated by a strong hydrogen bond with a molecule of acetic acid balances the charge of the compound.
    • ISSN:
      1865-7117
      0932-0776
    • الرقم المعرف:
      edsair.doi.dedup.....76d65e0d0ebaa54a89d1bd5bcd7be7c4