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Probing Redox Non‐Innocence in Iron–Carbene Complexes {Fe=C(H)Ar} 10–11 by 1,2 H and 13 C Pulse Electron Paramagnetic Resonance

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  • معلومة اضافية
    • بيانات النشر:
      Wiley, 2021.
    • الموضوع:
      2021
    • نبذة مختصرة :
      We report the synthesis and spectroscopic characterization of a series of iron-carbene complexes in redox states {Fe=C(H)Ar}10-11 . Pulse EPR studies of the 1,2 H and 13 C isotopologues of {Fe=C(H)Ar}11 reveal the high covalency of the Fe-carbene bonding, leading to a more even spin distribution than commonly observed for reduced Fischer carbenes.
    • ISSN:
      1521-3773
      1433-7851
    • الرقم المعرف:
      10.1002/anie.202110704
    • Rights:
      OPEN
    • الرقم المعرف:
      edsair.doi.dedup.....2212560a2e60664c975affd19f2b0a85