Soil mineral structural water loss during loss on ignition analyses

Water loss from soil minerals has been known to cause errors in the determination of soil organic matter when the loss on ignition (LOI) method is used. Unfortunately, no known published studies reliably quantify the range of structural water in the soil. To do this, 15 common reference minerals were analyzed by LOI to obtain their individual water loss. In addition, 14 upland, loamy soil samples and 3 wetland/hydric soil samples with varied mineral contents were analyzed to collect their X-ray powder diffraction spectra. Based upon X-ray spectra peak intensities, the modal abundance of minerals in each soil sample was determined using the RockJock computer program. The resultant modal weight percentages of all identified minerals in each soil sample were then multiplied by the LOI value for each mineral to obtain the mineral structural water loss (SWL) of that soil sample. For the 17 soil samples analyzed, the range of mineral water loss is 0.56 to 2.45%. Depending on the LOI values of the soil samples, the SWL:LOI ratios range from 0.04 to around 1.00. The SWL:LOI ratios are particularly low for top wetland soil when the LOI value is higher. The ratios are lower for surface soil samples than for subsurface soil samples because of the high LOI values in surface soil samples. Understanding soil mineral water loss and its relation to the LOI patterns from various environments is important for the accurate evaluation of soil organic matter when the LOI method is used. Key words: Mineral, structural water, loss on ignition