Electro-Synthesis of Organic Compounds with Heterogeneous Catalysis.

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Publisher: WILEY-VCH Country of Publication: Germany NLM ID: 101664569 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 2198-3844 (Electronic) Linking ISSN: 21983844 NLM ISO Abbreviation: Adv Sci (Weinh) Subsets: MEDLINE

Original Publication: Weinheim : WILEY-VCH, [2014]-

Electro-organic synthesis has attracted a lot of attention in pharmaceutical science, medicinal chemistry, and future industrial applications in energy storage and conversion. To date, there has not been a detailed review on electro-organic synthesis with the strategy of heterogeneous catalysis. In this review, the most recent advances in synthesizing value-added chemicals by heterogeneous catalysis are summarized. An overview of electrocatalytic oxidation and reduction processes as well as paired electrocatalysis is provided, and the anodic oxidation of alcohols (monohydric and polyhydric), aldehydes, and amines are discussed. This review also provides in-depth insight into the cathodic reduction of carboxylates, carbon dioxide, CC, C≡C, and reductive coupling reactions. Moreover, the electrocatalytic paired electro-synthesis methods, including parallel paired, sequential divergent paired, and convergent paired electrolysis, are summarized. Additionally, the strategies developed to achieve high electrosynthesis efficiency and the associated challenges are also addressed. It is believed that electro-organic synthesis is a promising direction of organic electrochemistry, offering numerous opportunities to develop new organic reaction methods.
(© 2022 The Authors. Advanced Science published by Wiley-VCH GmbH.)

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22272150 National Natural Science Foundation of China; LD22B030002 Major Program of Zhejiang Provincial Natural Science Foundation of China; 2021R51009 Zhejiang Provincial Ten Thousand Talent Program; 2020ZS03 Independent Designing Scientific Research Project of Zhejiang Normal University; 2020-1-044 Key Science and Technology Project of Jinhua City; 2021ZS0604 Self Designed Scientific Research of Zhejiang Normal University

Keywords: electro-organic synthesis; heterogeneous catalysts; paired electrolysis; reactor engineering; value-added chemicals

Date Created: 20221118 Latest Revision: 20240910

20240910

PMC9811472

10.1002/advs.202205077

36398622