Toward Green Atom Transfer Radical Polymerization: Current Status and Future Challenges.

Publisher: WILEY-VCH Country of Publication: Germany NLM ID: 101664569 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 2198-3844 (Electronic) Linking ISSN: 21983844 NLM ISO Abbreviation: Adv Sci (Weinh) Subsets: MEDLINE

Original Publication: Weinheim : WILEY-VCH, [2014]-

Polymers*/chemistry; Polymerization

Reversible-deactivation radical polymerizations (RDRPs) have revolutionized synthetic polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with controlled architecture, composition, and functionality. Atom transfer radical polymerization (ATRP) has evolved beyond traditional polymer field, enabling synthesis of organic-inorganic hybrids, bioconjugates, advanced polymers for electronics, energy, and environmentally relevant polymeric materials for broad applications in various fields. This review focuses on the relation between ATRP technology and the 12 principles of green chemistry, which are paramount guidelines in sustainable research and implementation. The green features of ATRP are presented, discussing the environmental and/or health issues and the challenges that remain to be overcome. Key discoveries and recent developments in green ATRP are highlighted, while providing a perspective for future opportunities in this area.
(© 2022 The Authors. Advanced Science published by Wiley-VCH GmbH.)

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1620/MOB/V/2017/0 Polish Ministry of Education and Science; PPN/BEK/2018/1/00261 Polish National Agency for Academic Exchange; PL/2019/SR/41 Polish-U.S. Fulbright Commission - Senior Award; National Science Foundation; CHE 2000391 Division of Chemistry

Keywords: atom transfer radical polymerization; biobased polymers; degradable polymers; depolymerization; green chemistry

0 (Polymers)

Date Created: 20220217 Date Completed: 20220708 Latest Revision: 20240831

20240831

PMC9259732

10.1002/advs.202106076

35175001