Use of agricultural bio-wastes to remove arsenic from contaminated water.

Publisher: Kluwer Academic Publishers Country of Publication: Netherlands NLM ID: 8903118 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1573-2983 (Electronic) Linking ISSN: 02694042 NLM ISO Abbreviation: Environ Geochem Health Subsets: MEDLINE

Publication: 1999- : Dordrecht : Kluwer Academic Publishers
Original Publication: Kew, Surrey : Science and Technology Letters, 1985-

Arsenic*/analysis ; Drinking Water*/analysis ; Water Pollutants, Chemical*/analysis ; Saccharum* ; Groundwater*/chemistry; Cellulose ; Risk Assessment/methods ; Agriculture

Arsenic (As) is a highly toxic metalloid. High As levels have been recorded in groundwater aquifers at a global scale. This study investigated As level in groundwater of District Vehari and assessed the potential of different agricultural by-products (sugarcane bagasse, cottonseed hulls, soybean hulls, corncobs and rice husk) to remove As from water. The study was carried out in two steps. In the first step, a total of 38 groundwater samples were obtained from Vehari. Groundwater samples were analyzed for total As contents and physicochemical parameters. Results indicated that As content ranged from below detection limit to 49 µg/L in the groundwater samples. The values of hazard quotient and cancer risk were up to 1.5 and 0.0004, respectively, which delineated severe risk of As poisoning. During the second step, six As-contaminated groundwater samples (total As contents: 49, 40, 29, 24, 18, 16 µg/L) were selected to remove As using agricultural by-products. Furthermore, four As solutions (200, 100, 50 and 25 µg/L) were prepared in the laboratory. Results revealed that corncobs and soybean hulls removed, respectively, 98% and 71% As from aqueous mediums after 120 min. Moreover, agricultural by-products were less effective in removing As from groundwater samples than synthetic solutions. The adsorption/removal capacity of by-products was lower at low initial As concentration compared to high initial levels, which needs further studies to explore the underlying mechanisms. Overall, the As removal efficiency of agriculture by-products differed significantly with respect to initial As level, contamination category, type of agricultural by-products and interaction duration. Therefore, these aspects need to be optimized before the possible use of an agricultural by-product as a potential biosorbent.
(© 2020. Springer Nature B.V.)

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16-25/CRGP/CIIT/VEH/17/1141 COMSATS Institute of Information Technology; 7770/Federal/ NRPU/R&D/HEC/ 2017 Higher Education Commission, Pakistan

Keywords: Agriculture biosorbents; Arsenic; Drinking water; Remediation; Risk assessment

0 (Arsenic-71)
N712M78A8G (Arsenic)
9004-34-6 (Cellulose)
0 (Drinking Water)
0 (Water Pollutants, Chemical)

Date Created: 20201125 Date Completed: 20230807 Latest Revision: 20230827

20240513

10.1007/s10653-020-00782-1

33236273