Ion and molecular recognition using aryl-ethynyl scaffolding.

Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 101294643 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1861-471X (Electronic) Linking ISSN: 1861471X NLM ISO Abbreviation: Chem Asian J Subsets: MEDLINE

Original Publication: Weinheim, Germany : Wiley-VCH, c2006-

Alkynes/*chemistry ; Chemical Engineering/*methods; Chemistry Techniques, Synthetic ; Molecular Probes ; Molecular Structure

The aryl-ethynyl linkage has been extensively employed in the construction of hosts for a variety of guests. Uses range from ion detection (e.g., of metal cations in the environment or industrial waste and of anions prevalent in nature), to molecular mimics for biological systems, and to applications targeting future safety issues (such as CO2 capture and indicators for the manufacture of chemical weapons). This Focus Review examines the utilization of the aryl-ethynyl linkage in engineering host molecules for a variety of different guests, and how the alkyne unit plays an integral part as both a rigid scaffolding section in host geometry design as well as a linker to allow conjugative communication between discrete π-electron systems.
(© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

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R01 GM087398 United States GM NIGMS NIH HHS; R01-GM087398 United States GM NIGMS NIH HHS

Keywords: aryl-ethynyl; fluorescent probes; host-guest systems; sensors; supramolecular chemistry

0 (Alkynes)
0 (Molecular Probes)

Date Created: 20150115 Date Completed: 20151103 Latest Revision: 20181113

20231215

PMC4567383

10.1002/asia.201403212

25586943