Determination of lead ions in fish and oyster samples using a nano-adsorbent of functionalized magnetic graphene oxide nanosheets-humic acid and the flame atomic absorption technique.

This study aims at the functionalization of magnetic graphene oxide nanosheets and the binding of humic acid as a lead complex ligand. Graphene oxide nanosheets possess a large surface area and various carboxylic acid groups which can be activated easily by activating agents. Therefore, they are suitable to be used for the extraction of heavy metals. To have a better process of extracting lead ions, magnetic graphene oxide was used in this research. Humic acid, as a lead metal complex agent, has an amine functional group which can be bound to modified graphene oxide from one side. The process of constructing the nano-adsorbent proposed for the preconcentration of lead ions as well as its characterization was studied by infrared spectroscopy (IR), ultraviolet–visible spectroscopy (UV–visible), field emission scanning electron microscopy (FESEM), and vibrating sample magnetometry (VSM). The designed nano-adsorbent was tested to measure lead ions in simulated and real samples of sea water, fish, and oysters. The detection limit obtained in the simulated samples was 0.07 μg/L, and the linear range was 0.2–12 μg/L. The apparatus used to measure the ions was a flame atomic absorption device. In the analysis of the real samples, the values obtained through flame atomic absorption were compared with those obtained through furnace atomic absorption. The proposed technique is advantageous due to being cheap, precise, and sensitive for the trace measurement of lead ions. [ABSTRACT FROM AUTHOR]

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