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Solar-driven semi-conductor photocatalytic water treatment (TiO 2 , g-C 3 N 4 , and TiO 2 +g-C 3 N 4 ) of cyanotoxins: proof-of-concept study with microcystin-LR

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  • معلومة اضافية
    • الموضوع:
      2023
    • Collection:
      Queen's University Belfast: Research Portal
    • نبذة مختصرة :
      Cyanobacteria and their toxins are a threat to drinking water safety as increasingly cyanobacterial blooms (mass occurrences) occur in lakes and reservoirs all over the world. Photocatalytic removal of cyanotoxins by solar light active catalysts is a promising way to purify water at relatively low cost compared to modifying existing infrastructure. We have established a facile and low-cost method to obtain TiO 2 and g-C 3 N 4 coated floating photocatalysts using recycled glass beads. g-C 3 N 4 coated and TiO 2 +g-C 3 N 4 co-coated beads were able to completely remove microcystin-LR in artificial fresh water under both natural and simulated solar light irradiation without agitation in less than 2 h. TiO 2 coated beads achieved complete removal within 8 h of irradiation. TiO 2 +g-C 3 N 4 beads were more effective than g-C 3 N 4 beads as demonstrated by the increase reaction rate with reaction constants, 0.0485 min−1 compared to 0.0264 min−1 respectively, with TiO 2 alone found to be considerably slower 0.0072 min−1. g-C 3 N 4 based photocatalysts showed a similar degradation pathway to TiO 2 based photocatalysts by attacking the C6–C7 double bond on the Adda side chain.
    • File Description:
      application/pdf
    • الرقم المعرف:
      10.1016/j.chemosphere.2022.136828
    • الدخول الالكتروني :
      https://pure.qub.ac.uk/en/publications/22d5f7ad-7596-477d-89ba-e9ce705b47d0
      https://doi.org/10.1016/j.chemosphere.2022.136828
      https://pureadmin.qub.ac.uk/ws/files/382404066/Solar_driven_semi_conductor_photocatalytic_water_treatment_TiO2_g_C3N4_and_TiO2_g_C3N4_of_cyanotoxins_proof_of_concept_study_with_microcystin_LR.pdf
    • Rights:
      info:eu-repo/semantics/openAccess
    • الرقم المعرف:
      edsbas.F8E2816F